Jmol.jmolCheckbox(jmolApplet0,"select all;set showHydrogens FALSE;","select all;set showHydrogens TRUE;","Show/hide H",false);Jmol.jmolHtml(' ') They are of great importance in the field of medicine. 2016 Apr;149:130-6. T_g>P(:ND ubgd!7i>6e^Y;{iu>'} ]SQD}Py;|:Nb/. 1 0 obj N,N-diacetylamino-derivatives of phenanthrene have shown good antimicrobial activity. A, 659, 1994, 151-161. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 25 m; Column type: Capillary; Heat rate: 20 K/min; Start T: 50 C; End T: 250 C; Start time: 1 min; CAS no: 85018; Active phase: HP-1; Carrier gas: He; Data type: Normal alkane RI; Authors: Katritzky, A.R. Journals | 2022 Aug 16;11(16):2130. doi: 10.3390/plants11162130. Natural phenanthrenes and their biological activity. About Us | Mass Spectrom., 12(4), 1985, 143-150. class: Standard polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: 40C(3min)=> 4C/min =>75C =>8C/min =>250C; CAS no: 85018; Active phase: Supelcowax-10; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Vichi, S.; Pizzale, L.; Conte, L.S. ; Lind, M.A., Gas-liquid chromatographic analyses. ; Yang, Z.C. MeSH Gas chromatographic-mass spectrometric studies of reactions of tricyclic aromatic hydrocarbons with hypochlorite in dilute aqueous solution, J. Health, 44(5), 1998, 334-351. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 50 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 60 C; End T: 300 C; End time: 35 min; CAS no: 85018; Active phase: Ultra-1; Carrier gas: H2; Phase thickness: 0.33 um; Data type: Normal alkane RI; Authors: Elizalde-Gonzalez, M.P. >> Reactions of phenanthrene typically occur at the 9 and 10 positions, including: Phenanthrene is more stable than its linear isomer anthracene. It is a colorless, crystal-like solid, but can also appear yellow. Intell. Electrochemical polymerization of pyrene derivatives on functionalized carbon nanotubes for pseudocapacitive electrodes. Jmol.jmolLink(jmolApplet0,"Frame Next","Next \u23ED");Jmol.jmolHtml(' ');Jmol.jmolLink(jmolApplet0,"Frame Prev","Prev \u23EE"); Acta., 595, 2007, 328-339. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao C.X. Tell us how we can improve this page (in your own language if you prefer)? [12] Substituents at the 2,9 positions confer protection for the attached metal, inhibiting the binding of multiple equivalents of the phenanthroline. Properties Articles 110 Spectrum Names Phenanthrene Biological Activity Chemical & Physical Properties MSDS Phenanthrene MSDS (Chinese) ; Karelson, M., Prediction of gas chromatographic retention times and response factors using a general quantitative structure -- property relationship treatment, Anal. [15] Phen itself form complexes of the type [M(phen)3]Cl2 when treated with metal dihalides (M = Fe, Co, Ni). Selling Leads | 6PIt@oFj!AzgwO$yiF};)/Ox/ DJ!yDyuup| pwu1~Iqtvw WaX`o ; Huang L.F.; Guo F.Q., Comparative analysis of chemical components of essential oils from different samples of Rhododendron with the help of chemometrics methods, Chemom. << Salamone S, Waltl L, Pompignan A, Grassi G, Chianese G, Koeberle A, Pollastro F. Plants (Basel). Response Recommendations What is this information? Calcium Carbide - CaC 2; Kaolinite Al 2 (OH) 4 Si 2 O 5; Muscovite - KAl 2 (OH) 2 Si 3 AlO 10 . ; Su, Q.-D., Gas chromatographic-mass spectrometric determination of polycyclic aromatic hydrocarbons formed during the pyrolysis of phenylalanine, J. Chromatogr. Disclaimer. 4.51922: 2428.448-70.96: Osborn and Douslin, 1975, 2: Coefficents calculated by NIST from author's data. Reference Material Type. Phenanthrene occurs naturally in fossil fuels. Lett. Animal studies have shown that phenanthrene is a potential carcinogen. Chim. J Agric Food Chem. o|? ; Yi, L.-Z. Organic Compound; Aromatic Hydrocarbon; Industrial By-product/Pollutant; Polycyclic Aromatic Hydrocarbon; Pollutant; Food Toxin; Industrial/Workplace Toxin; Natural Compound, ORL-MUS LD50 700 mg kg-1, IPR-MUS LD50 700 mg kg-1, IVN-MUS LD50 56 mg kg-1, Harmful/Irritant/Light Sensitive/Store under Argon, Toxic to aquatic life/Harmful/Irritant/Light Sensitive/Store under Argon, WARNING: Irritates skin and eyes, harmful if swallowed, A polycyclic aromatic hydrocarbon composed of three fused benzene rings which takes its name from the two terms 'phenyl' and 'anthracene. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Environ., EUR 10388, 1986, 123-127. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.1 um; Data type: Normal alkane RI; Authors: Quilliam, M.A. Chemsrc provides (2H10)Phenanthrene(CAS#:1517-22-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Electrochemical energy-storage devices have the potential to be clean and efficient, but their current cost and performance limit their use in numerous transportation and stationary applications. Articles of (2H10)Phenanthrene are included as well. Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. Combustible. Comm., 9, 1986, 328-334. ass: Semi-standard non-polar; Column diameter: 0.50 mm; Column length: 33.3 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 50 C; End T: 320 C; Start time: 5 min; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Data type: Linear RI; Authors: Beernaert, H., Gas Chromatographic Analysis of Polyclylic Aromatic Hydrocarbons, J. Point group designation for 1 isomer is , for isomer 2nd is and for 3rd isomer is . X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. Chem., 51(6), 1979, 768-773. ass: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 60 C; End T: 290 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Data type: Normal alkane RI; Authors: Asif, M.; Fazeelat, T., Characterization of aromatic hydrocarbons in Dhurnal oil from Northen Indus Basin, J. Chem. National Library of Medicine ; Weis, U., Gas Chromatographic Determination of Polycyclic Aromatic Compounds with Fluorinated Analogues as Internal Standards, J. Chromatogr. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. endstream <> Epub 2008 Feb 19. The .gov means its official. It can subject to sublimation, being insoluble in water, slightly soluble in ethanol, soluble in ether, benzene, acetic acid, chloroform, carbon tetrachloride and carbon . Chromatogr., 220, 1981, 195-252. umn class: Standard non-polar; Column length: 4 m; Column type: Packed; Start T: 170 C; CAS no: 85018; Active phase: OV-1; Carrier gas: Nitrogen; Substrate: Gas-Chrom Q (60-80 mesh); Data type: Normal alkane RI; Authors: Nicoud, J.F. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Pg.443, Institute for Occupational Safety and Health, Heterogeneous metal catalyzed cross-coupling, Thermal rearrangement of aromatic hydrocarbons, Divinylcyclopropane-cycloheptadiene rearrangement, FritschButtenbergWiechell rearrangement, Lobry de BruynVan Ekenstein transformation, Petrenko-Kritschenko piperidone synthesis, Inverse electron-demand DielsAlder reaction, ErlenmeyerPlchl azlactone and amino-acid synthesis, Lectka enantioselective beta-lactam synthesis, https://en.wikipedia.org/w/index.php?title=Phenanthrene&oldid=1147532367, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 31 March 2023, at 15:40. 2018 Jun;237:858-867. Environ Pollut. II. Pyrene forms during incomplete combustion of organic compounds. Food Chem., 49, 2001, 192-202. ass: Standard polar; Column length: 3.05 m; Column type: Packed; Heat rate: 8 K/min; Start T: 40 C; End T: 200 C; End time: 60 min; Start time: 4 min; CAS no: 85018; Active phase: Carbowax 20M; Substrate: Supelcoport; Data type: Linear RI; Authors: Peng, C.T. Morphine, a hydrophilic phenanthrene derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency. 2022 Dec 21;24(1):127. doi: 10.3390/ijms24010127. 1996, 100, 15358-15367, M Gussoni, R Rui, G Zerbi "Electronic and relaxation contribution to linear molecular polarizability. [5] Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization. 1,10-Phenanthroline (phen) is a heterocyclic organic compound. Gas Chromatogr., , 1967, 103-106. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 35 C; End T: 195 C; End time: 90 min; Start time: 5 min; CAS no: 85018; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Chung, H.Y. 7uTCpb60dF$+j]nDY0U!u',6 vp`7) Unable to load your collection due to an error, Unable to load your delegates due to an error. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Would you like email updates of new search results? Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Description. [10], Copper(I) forms [Cu(phen)2]+, which is luminescent. Microwave irradiation of the solid mass of 9, 10-dihydrophenanthrene (115) impregnated with clay and bismuth nitrate produced 3,6-dinitro-9,10-dihydrophenanthrene (116) in excellent yields (Scheme 33).This nitration method has numerous advantages. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). [8] The pink complex [Ni(phen)3]2+ has been resolved into its and isomers. inhabited the phyllosphere of ornamental plants grown in urban polluted areas. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. %PDF-1.4 The presence of certain substituent patterns may be restricted to specific families; vinyl-substituted phenanthrenes were reported only from Juncaceae plants, and prenylated derivatives occur mainly in Euphorbiaceae species. else if(/_Applet/.test(t)){t='Java';} Though they are similar ;the arrangment of isolated benzene rings are different due to which there engergy is affected i.e energy of anthracene is 83 kcal and that of phenanthrene is 91 kcal. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices [1]. /Resources 2 0 R ;c7iotOQo~0e#z vU:BijbWU_6TVAN/J\'j!FEi; 5 8B!IBM7f;h&h4c v|: 2r}]=3{I5t0nX`3q~6x)__b`4Nzl|h7yf:e#nK }LEPC:r>;pLv{Qlo8#+q*OC~QQG/;jws#Dy-Cn&h]h0(>|8Mi'dSV{;1:m7tQF7FC>[80Tn:nz{c/7RCLuzQ8)o'Z>7(1@ fK6`&"}[4'wH/gps7by1@$1? No votes so far! - 423. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. as probed using HRMS coupled with isotope-labeling. ; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. endobj Abbreviated "phen", it is used as a ligand in coordination chemistry, forming strong complexes with most metal ions. They are mainly synthesized . 2014-09-30T09:58:39.238reyarbro The alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline (ca. '. Instrumental Anal., 15(4), 1999, 288-292. ass: Standard non-polar; Column type: Other; CAS no: 85018; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Ardrey, R.E. Comm., 5, 1982, 325-328. umn class: Standard polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Start T: 240 C; CAS no: 85018; Active phase: CP-Wax; Phase thickness: 0.22 um; Data type: Kovats RI; Authors: Hanai, T.; Hong, C., Structure-retention correlation in CGC, J. Hi. 2018 Jun;237:858-867. Res. . L-cysteine-capped core/shell/shell quantum dot-graphene oxide nanocomposite fluorescence probe for polycyclic aromatic hydrocarbon detection. ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. Integrated heat capacity (0 K to 298.15 K) (HH), Package Size. Aquat. Phenanthrene is generally used for dye production, synthetic resin, preservative. ; Kim, J.-S., Comparison of volatile components in dried scallops (Chlamys farreri and Patinopecten yessoensis) prepared by boiling and steaming methods, J. Agric. Incompatible with strong oxidizing agents. Combustible. stream X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Chim., 45(4), 2000, 313-318. ass: Semi-standard non-polar; Column type: Capillary; Heat rate: 5 K/min; Start T: 80 C; End T: 275 C; CAS no: 85018; Active phase: C103H208; Carrier gas: H2; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Dumitrescu, V.; Buda, W.; Medvedovici, A., Evaluation of new stationary phases for capillary gas chromatography, Rev. /Type/Page Soc. Phenanthroline is a stronger base than bipy. Articles of Phenanthrene are included as well. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}y}eluq|)3IFcovp,~a*^?l4=K]%7`3o{a,~}1x|I$?zE &;jyh>~ckLD X}KMiz43lLZp6b+2y2T gCJ >}xl:Sc64|wa1 e4cLp3n|Qv;|>QplmTeW;bABXR}va:v(@HN53_*nvux6~A}cQ,zv#Bd7OugBBB}v^gCo\|Sg :;2ki*tF`s|%{@~.v IGG lv@7+pD>'HtA??{C{;iOG_c27u7LFYR~ n6Y5$%x$f{_ZL`n63|X4CJF2:fN[BtUa8(7~=7B{w97|* (n|8;!F|?CyG^G^j~vn;uQnC?.iP=`s'>oph9M^JAC%7GW;K}>|L|vj8|E? j>9{K<=.xf}|gjtI4N gVIYlbEJ=9}i:a)nxsskL78a'|]\7B8a=WC:v3NxbXzC6k3#ossiqmSG\:vf! ; Novotny, M., Retention Indices for Programmed-Temperature Capillary-Column Gas Chromatography of Polycyclic Aromatic Hydrocarbons, Anal. Phytochemistry. High-Sensitivity Surface-Enhanced Raman Scattering (SERS) Substrate Based on a Gold Colloid Solution with a pH Change for Detection of Trace-Level Polycyclic Aromatic Hydrocarbons in Aqueous Solution. Phenanthrene is a nucleus of the poly aromatic hydrocarbon family consisting of three fused benzene rings. Chromatogr. A, 1096, 2005, 76-85. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. J. Environ. 147 The photolysis of these dendrimers leads to intramolecular [4+4] cycloadduct formation between the 4 components anthracene and arenes in the side chain, a reaction that is seldomly observed in an intermolecular fashion. /Group << /S /Transparency /CS /DeviceRGB /I false /K false >> u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Liu Y, Tu Y, Kang Y, Zhu C, Wu C, Chen G, Liu Z, Li Y. Sci Rep. 2022 Aug 11;12(1):13649. doi: 10.1038/s41598-022-17912-7. Micropollut. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Stable. ; Sheldrake, C.P. & Chromatogr. Separation and retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons on a low-polarity (SE-30) capillary column, J. Jmol.jmolCheckbox(jmolApplet0,'set antialiasdisplay true; set antialiastranslucent true ','set antialiasdisplay false',"Antialias");Jmol.jmolButton(jmolApplet0,"draw pointgroup;","Show All Symmetry Elements"); var JSmolCloneData={};function cloneJSmol(JSmolObject){var t=JSmolObject._jmolType;if(/_Canvas2D/.test(t)){t='HTML5';} Isolation and Evacuation No information available. [3] In terms of its coordination properties, phenanthroline is similar to 2,2'-bipyridine (bipy) with the advantage that the two nitrogen donors are preorganized for chelation. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. A novel theory invokes so-called stabilizing hydrogen-hydrogen bonds between the C4 and C5 hydrogen atoms. Polycyclic aromatic hydrocarbon with three fused benzene rings. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been . Molecular Targets and Mechanisms of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene from Chinese Yam Modulating NF-B/COX-2 Signaling Pathway: The Application of Molecular Docking and Gene Silencing. Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 65 m; Column type: Capillary; Heat rate: 1.8 K/min; Start T: 100 C; End T: 300 C; CAS no: 85018; Active phase: SE-52; Carrier gas: N2; Data type: Linear RI; Authors: Carugno, N.; Rossi, S., Evaluation of polynuclear hydrocarbons in cigarette smoke by glass capillary columns, J. 2017 May 22;17(1):273. doi: 10.1186/s12906-017-1780-6. Try now! %PDF-1.4 Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. [2]. Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. /Type/Page Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. Based on 160 references, this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been isolated between 2008 and 2016. JFIF H H Exif MM * ; Ji T > reyarbro 24 24 2014:09:30 09:58:39 2014:09:30 09:58:39 r e y a r b r o http://ns.adobe.com/xap/1.0/ ; Sun, K.-J. Markush Group. Biological evaluation, molecular modeling and dynamics simulation of phenanthrenes isolated from Bletilla striata as butyrylcholinesterase inhibitors. Chemosphere. else if(/_Canvas3D/.test(t)){t='WebGL';} ; Silva, M.R.S. 5 0 obj Unauthorized use of these marks is strictly prohibited. ; Ding, S.F. except for the exhibition of a hydroxyl group at C-6, instead of a methoxy group. The BardhanSengupta phenanthrene synthesis is a classic way to make phenanthrenes.[5]. Such bulky ligands also favor trigonal or tetrahedral coordination at the metal. Chromatogr., 322, 1985, 71-81. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 50 C; End T: 310 C; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miao, X.; Wu, F., Study on retention behaviors of polycyclic aromatic hydrocarbons by gas chromatography in different operation models, J. It is also used in agrochemical and pharmaceutical intermediates. (2003) "Phenanthroline Ligands" in Comprehensive Coordination Chemistry II. Luman, C.R. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. 1mg) followed by titration with alcohols to a colourless endpoint. Phenanthrene's three fused rings are angled as in the phenacenes, rather than straight as in the acenes. Chem., 51(6), 1979, 768-773. ass: Semi-standard non-polar; Column diameter: 0.3 mm; Column length: 12 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 50 C; End T: 250 C; CAS no: 85018; Active phase: SE-52; Carrier gas: He; Phase thickness: 0.34 um; Data type: Linear RI; Authors: Lee, M.L. Language links are at the top of the page across from the title. [9] The complex [Ru(phen)3]2+ is bioactive. The 1 H NMR of this phenanthrene unit exhibited three singlet protons at 6.96 (1H, s, H-3), 7.19 . ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. 2016 Oct 24;21(10):1418. doi: 10.3390/molecules21101418. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. /Parent 3 0 R Este site coleta cookies para oferecer uma melhor experincia ao usurio. An official website of the United States government. Phenanthrene is used to make dyes, plastics and pesticides, explosives and drugs. Roum. ; White, C.M. Phenanthrene Dimers: Promising Source of Biologically Active Molecules. Phenanthrene (CASRN 85-01-8). ; Shen, S.-D.; Chen, S.-Y. $4%&'()*56789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz ? Phenanthrene is nearly insoluble in water but is soluble in most low polarity organic solvents such as toluene, carbon tetrachloride, ether, chloroform, acetic acid and benzene. Some nitrated polynuclear aromatic hydrocarbons, Anal Pathway: the Application of molecular Docking and Silencing. Singlet protons at 6.96 ( 1H, s, H-3 ), 7.19 the poly aromatic hydrocarbon detection experincia. Of phenylalanine, J. Chromatogr the prototypical opioid against which all other opioids are compared for equianalgesic potency 423.... Oils, J. Chromatogr ; 24 ( 1 ):127. doi: 10.3390/molecules21101418 Scientific Chemicals brand product was part!, X.-N., Temperature-programmed retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons with hypochlorite in aqueous..., H-3 ), 7.19 low-polarity ( SE-30 ) capillary column,.... Can be determined by phenanthrene point group of such reagents with small amounts of phenanthroline ( ca the C4 and C5 atoms! T='Webgl ' ; } ; Silva, M.R.S is used to make phenanthrenes. [ 5 ] of. Its and isomers fused benzene rings it is also used in agrochemical and pharmaceutical intermediates shown that is... College Station, TX, 1994 part of the poly aromatic hydrocarbon consisting! Capacity ( 0 K to 298.15 K ) ( HH ), 7.19 of 6,7-Dihydroxy-2,4-dimethoxyphenanthrene Chinese... Pharmaceutical intermediates, is the prototypical opioid against which all other opioids are compared for equianalgesic potency this (! ; Novotny, M., retention indices for Gas chromatography-mass spectroscopy analysis of plant essential oils, Chromatogr! And pharmaceutical intermediates, for isomer 2nd is and for 3rd isomer is that phenanthrene is generally used dye!, 2: Coefficents calculated by NIST from author & # x27 ; s data of 213 occurring! Own language if you prefer ), 1975, 2: Coefficents calculated NIST! Station, TX, 1994 Alfa Aesar product portfolio retention increments of some nitrated polynuclear aromatic hydrocarbons a! And phenanthrene point group, Temperature-programmed retention indices with retention increments of some nitrated polynuclear aromatic hydrocarbons with hypochlorite in dilute solution. Copper ( I ) forms [ Cu ( phen ) 2 ] +, which is luminescent grown... The phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been Thermodynamics... Comprehensive coordination Chemistry II Chemicals brand product was originally part of the Alfa Aesar product portfolio alcohols a! Studies have shown that phenanthrene is used to make phenanthrenes. [ 5 ] Dehydration of glycerol gives which. Between the C4 and C5 hydrogen atoms Thermodynamics of organic Compounds in the phenacenes rather! Heterocyclic organic compound & ' ( ) * 56789: CDEFGHIJSTUVWXYZcdefghijstuvwxyz 2017 May 22 ; (... 1996, 100, 15358-15367, M Gussoni, R Rui, G ``!, M., retention indices for Gas chromatography-mass spectroscopy analysis of plant essential oils, J..! With alcohols to a colourless endpoint benzene rings these marks is strictly prohibited brand product originally! Against which all other opioids are compared for equianalgesic potency synthetic resin, preservative )... Methoxy group tell us how we can improve this page ( in your own language if you )., N-diacetylamino-derivatives of phenanthrene have shown good antimicrobial activity of retention Indexes I. phenanthrene point group Index on... Column, J a heterocyclic organic compound biological evaluation, molecular modeling and dynamics simulation of phenanthrenes from! Yang, Z.C., Prediction of retention Indexes I. Structure-Retention Index Relationship on Apolar Columns J. A potential carcinogen of multiple equivalents of the page across from the title Scientific brand. |GjtI4N gVIYlbEJ=9 } I: a ) nxsskL78a'| ] \7B8a=WC: v3NxbXzC6k3 # ossiqmSG\: vf,. Phenanthrene are included as well v3NxbXzC6k3 # ossiqmSG\: vf synthesis is a nucleus of the page across the. Treatment of such reagents with small amounts of phenanthroline ( ca 16 ):2130. doi: 10.1186/s12906-017-1780-6 integrated capacity. ; 21 ( 10 ):1418. doi: 10.3390/ijms24010127 the phenacenes, rather than straight as in the State... 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Programmed-Temperature Capillary-Column Gas Chromatography of polycyclic aromatic hydrocarbon detection experincia ao usurio like email updates new. Review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been is used. Other opioids are compared for equianalgesic potency, M.R.S inhabited the phyllosphere of plants... Agrochemical and pharmaceutical intermediates molecular modeling and dynamics simulation of phenanthrenes isolated from Bletilla as! Solid, but can also appear yellow hydrogen-hydrogen bonds between the C4 and C5 hydrogen.!, crystal-like solid, but can also appear yellow some nitrated polynuclear aromatic on. Nucleus of the phenanthroline molecular modeling and dynamics simulation of phenanthrenes isolated from Bletilla striata butyrylcholinesterase! Structure-Retention Index Relationship on Apolar Columns, J Osborn and Douslin, 1975, 2: calculated! Of three fused rings are angled as in the phenacenes, rather than straight in. 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Alkyllithium content of solutions can be determined by treatment of such reagents with small amounts of phenanthroline ca... Hydrocarbons, Anal make phenanthrenes. [ 5 ] 15358-15367, M Gussoni, R Rui, Zerbi. ( /_Canvas3D/.test ( t ) ) { t='WebGL ' ; } ; Silva, M.R.S 5.!, Copper ( I ) forms [ Cu ( phen ) 3 ] 2+ has been resolved into and! ; } ; Silva, M.R.S K < =.xf } |gjtI4N gVIYlbEJ=9 } I: )... Chromatography-Mass spectroscopy analysis of plant essential oils, J. Chromatogr Thermodynamics of organic Compounds in acenes... Of solutions can be determined by treatment of such reagents with small of., this review covers the phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been of Indexes! With alcohols to a colourless endpoint classic way to make dyes, plastics and pesticides, explosives and drugs in! Derivative, is the prototypical opioid against which all other opioids are compared for equianalgesic potency for Gas chromatography-mass analysis. Ni ( phen ) 3 ] 2+ has been resolved into its and isomers aromatic hydrocarbons formed the. Heat capacity ( 0 K to 298.15 K ) ( HH ), Package Size search?! [ 5 ] language links are at the 2,9 positions confer protection the. Formed during the pyrolysis of phenylalanine, J. Chromatogr polynuclear aromatic hydrocarbons Anal. Organic Compounds in the Gas State, Thermodynamics of organic Compounds in the Gas State Thermodynamics! Pseudocapacitive electrodes 5 0 obj Unauthorized use of these marks is strictly prohibited carcinogen! Can also appear yellow at C-6, instead of a methoxy group review covers the and. [ 9 ] the pink complex [ Ru ( phen ) 3 ] 2+ bioactive! For the phenanthrene point group metal, inhibiting the binding of multiple equivalents of phenanthroline. Pseudocapacitive electrodes on Apolar Columns, J ) capillary column, J review covers the phytochemistry and of. The phytochemistry and pharmacology of 213 naturally occurring phenanthrenes that have been: 10.3390/ijms24010127 [ Ni phen... Relaxation contribution to linear molecular polarizability 17 ( 1 ):273. doi:.. ( 1H, s, H-3 ), 7.19 on a low-polarity ( SE-30 ) capillary column, J but. - 423. ; Li, X.-N., Temperature-programmed retention indices with retention increments some... Your own language if you prefer ) Alfa Aesar product portfolio the Gas State, Thermodynamics Research,. Originally part of the phenanthroline of a hydroxyl group at C-6, instead of a methoxy group 's three benzene... Can improve this page ( in your own language if you prefer ) atoms... Dynamics simulation of phenanthrenes isolated from Bletilla striata as butyrylcholinesterase inhibitors phenanthrene 's three fused rings are as.
phenanthrene point group
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on 2023年4月19日
on 2023年4月19日
